*Target (protein/gene name): Glutamine Synthetase GlnA1


*NCBI Gene #: 888383

*Protein ID (NP or XP #: MTCY190.31, MTCY427.01

*Organism (including strain): Mycobacterium tuberculosis (strain ATCC 25618/ H37Rv)

Etiologic Risk Group (see link below): Risk Group 2 (WHO)

*Background/Disease Information (sort of like the Intro to your Mini Research Write up):
Mycobacterium tuberculosis is the pathogen that causes tuberculosis, a virulent disease that has infected a large portion of the world's population. It is spread through aerosols, so actions such as coughing or sneezing from an infected individual may release the pathogen into the air. Once in the air, the pathogen may be taken into the body by others, increasing the spread of infection. Once the pathogen enters the body, it multiplies, causing a response from the immune system. This is why individuals who are immunodeficient are highly susceptible to tuberculosis. Though the pathogen normally targets the lungs, other parts of the body are susceptible too. The symptoms of this disease include chronic coughing, chest pain, general malaise, fever, chills, and even weight loss.

Link to TDR Targets page (if present):
http://tdrtargets.org/targets/view?gene_id=6148

Link to Gene Database page (NCBI, EuPath databases -e.g. TryTryp, PlasmoDB, etc - or PATRIC, etc.):
http://www.ncbi.nlm.nih.gov/gene/888383

Essentiality of this protein:
Glutamine synthetase is significant in metabolism of nitrogen within the pathogen. This enzyme catalyzes the condensation of glutamate and ammonia to form glutamine, one of the twenty amino acids. Without glutamine, synthesis of many proteins will be inhibited. Without a few of these proteins, the pathogen's viability will effectively reduced.

The essentiality data:

Gene/Ortholog: mtu2255 (OG4_10454); Phenotype: essential; Source study: nmpdr
Gene/Ortholog: mtu1908 (OG4_10454); Phenotype: non-essential; Source study: nmpdr
Gene/Ortholog: mtu2907 (OG4_10454); Phenotype: non-essential; Source study: nmpdr
Gene/Ortholog: mtu1909 (OG4_10454); Phenotype: non-essential; Source study: nmpdr
Gene/Ortholog: eco3728 (OG4_10454); Phenotype: non-essential; Source study: blattner
Gene/Ortholog: eco3728 (OG4_10454); Phenotype: non-essential; Source study: gerdes
Gene/Ortholog: eco3728 (OG4_10454); Phenotype: non-essential; Source study: keio
Gene/Ortholog: eco3728 (OG4_10454); Phenotype: non-essential; Source study: shigen

Complex of proteins?: No

Druggable Target (list number or cite evidence from a paper/database showing druggable in another organism):
Escherichia coli: http://www.ncbi.nlm.nih.gov/pubmed/16190760

*EC#: 6.3.1.2

Link to BRENDA EC# page:
http://www.brenda-enzymes.org/php/result_flat.php4?ecno=6.3.1.2

-- Show screenshot of BRENDA enzyme mechanism schematic

JS_ReactionMechanism.png
Figure 1- Brenda reaction mechanism of catalysis by glutamine synthetase in M. tuberculosis



Enzyme Assay information (spectrophotometric, coupled assay ?, reagents): Continuous Spectrophotometric Rate Determination
Reagents: 100 mM Imidazole HCL buffer, pH 7.1 at 37 degrees Celsius, 3M Sodium Glutamate Solution, 250mM Adenosine 5' Triphosphate solution

-- link to Sigma (or other company) page for assay (see Sigma links below)
http://www.sigmaaldrich.com/life-science/metabolomics/enzyme-explorer/learning-center/assay-library/ec-number-v.html#-%206%20-

-- links to assay reagents (substrates) pages.
http://www.sigmaaldrich.com/content/dam/sigma-aldrich/docs/Sigma/Enzyme_Assay/glutaminesynthetase.pdf

--- List cost and quantity of substrate reagents, supplier, and catalog #
Imidazole- $17.10, 1 gram, Sigma-Aldrich, I-0250
L-Glutamic acid monosodium salt monohydrate- $34.50, 250 grams, Sigma-Aldrich, 49621
Adenosine 5'-triphosphate disodium salt hydrate- $46.90, 1 gram, Sigma-Aldrich, A2383

Structure Available (PDB or Homology model)
-- PDB #: 1HTO

Current Inhibitors: Adenosine Monophosphate, Citric Acid, Manganese (II) Ion

Expression Information (has it been expressed in bacterial cells): Expression System was Escherichia coli

Purification Method:
E. coli cells are used to produce the glutamine synthetase. The cells then undergo centrifugation using GSA rotor at 4 degrees Celsius for 15 minutes. The pellets are suspended in 10mM of potassium phosphate/10mM 2-mercaptoethanol and centrifuged again. The cells are re-suspended in 10mL of phosphate buffer per gram of cells and put on ice for 10 minutes. Centrifugation follows. The supernatant is then loaded onto a hydroxyapatite column equilibrated in 10mM potassium phosphate/10mM 2-mercaptoethanol. The supernatant is eluted and the elution is centrifuged to collect the purified protein.

Image of protein (PyMol with features delineated and shown separately):
1HTO image.jpg
Figure 2- PyMOL representation of relaxed glutamine synthetase GlnA1 from Mycobacterium tuberculosis shown as cartoon; protein chains are colored from the N-terminal to the C-terminal using a rainbow color gradient

*Amino Acid Sequence (paste as text only - not as screenshot or as 'code')
MTEKTPDDVFKLAKDEKVEYVDVRFCDLPGIMQHFTIPASAFDKSVFDDGLAFDGSSIRG
FQSIHESDMLLLPDPETARIDPFRAAKTLNINFFVHDPFTLEPYSRDPRNIARKAENYLI
STGIADTAYFGAEAEFYIFDSVSFDSRANGSFYEVDAISGWWNTGAATEADGSPNRGYKV
RHKGGYFPVAPNDQYVDLRDKMLTNLINSGFILEKGHHEVGSGGQAEINYQFNSLLHAAD
DMQLYKYIIKNTAWQNGKTVTFMPKPLFGDNGSGMHCHQSLWKDGAPLMYDETGYAGLSD
TARHYIGGLLHHAPSLLAFTNPTVNSYKRLVPGYEAPINLVYSQRNRSACVRIPITGSNP
KAKRLEFRSPDSSGNPYLAFSAMLMAGLDGIKNKIEPQAPVDKDLYELPPEEAASIPQTP
TQLSDVIDRLEADHEYLTEGGVFTNDLIETWISFKRENEIEPVNIRPHPYEFALYYDV
*length of your protein in Amino Acids: 478

Molecular Weight of your protein in kiloDaltons using the Expasy ProtParam website: 53.57 kDa

Molar Extinction coefficient of your protein at 280 nm wavelength: 63385 M^-1 cm^-1

TMpred graph Image
TMPRED GS.gif
Figure 3- TMPred results of Glutamine synthetase GlnA1 from Mycobacterium tuberculosis


*CDS Gene Sequence (paste as text only):
        1 gtgacggaaa agacgcccga cgacgtcttc aaacttgcca aggacgagaa ggtcgaatat
       61 gtcgacgtcc ggttctgtga cctgcctggc atcatgcagc acttcacgat tccggcttcg
      121 gcctttgaca agagcgtgtt tgacgacggc ttggcctttg acggctcgtc gattcgcggg
      181 ttccagtcga tccacgaatc cgacatgttg cttcttcccg atcccgagac ggcgcgcatc
      241 gacccgttcc gcgcggccaa gacgctgaat atcaacttct ttgtgcacga cccgttcacc
      301 ctggagccgt actcccgcga cccgcgcaac atcgcccgca aggccgagaa ctacctgatc
      361 agcactggca tcgccgacac cgcatacttc ggcgccgagg ccgagttcta cattttcgat
      421 tcggtgagct tcgactcgcg cgccaacggc tccttctacg aggtggacgc catctcgggg
      481 tggtggaaca ccggcgcggc gaccgaggcc gacggcagtc ccaaccgggg ctacaaggtc
      541 cgccacaagg gcgggtattt cccagtggcc cccaacgacc aatacgtcga cctgcgcgac
      601 aagatgctga ccaacctgat caactccggc ttcatcctgg agaagggcca ccacgaggtg
      661 ggcagcggcg gacaggccga gatcaactac cagttcaatt cgctgctgca cgccgccgac
      721 gacatgcagt tgtacaagta catcatcaag aacaccgcct ggcagaacgg caaaacggtc
      781 acgttcatgc ccaagccgct gttcggcgac aacgggtccg gcatgcactg tcatcagtcg
      841 ctgtggaagg acggggcccc gctgatgtac gacgagacgg gttatgccgg tctgtcggac
      901 acggcccgtc attacatcgg cggcctgtta caccacgcgc cgtcgctgct ggccttcacc
      961 aacccgacgg tgaactccta caagcggctg gttcccggtt acgaggcccc gatcaacctg
     1021 gtctatagcc agcgcaaccg gtcggcatgc gtgcgcatcc cgatcaccgg cagcaacccg
     1081 aaggccaagc ggctggagtt ccgaagcccc gactcgtcgg gcaacccgta tctggcgttc
     1141 tcggccatgc tgatggcagg cctggacggt atcaagaaca agatcgagcc gcaggcgccc
     1201 gtcgacaagg atctctacga gctgccgccg gaagaggccg cgagtatccc gcagactccg
     1261 acccagctgt cagatgtgat cgaccgtctc gaggccgacc acgaatacct caccgaagga
     1321 ggggtgttca caaacgacct gatcgagacg tggatcagtt tcaagcgcga aaacgagatc
     1381 gagccggtca acatccggcc gcatccctac gaattcgcgc tgtactacga cgtttaa
*GC% Content for gene: 61.238%

*CDS Gene Sequence (codon optimized) - copy from output of Primer Design Protocol (paste as text only):
GTGACCGAAA AGACCCCGGA CGATGTTTTC AAACTGGCGA AAGACGAAAA AGTGGAATAC GTGGATGTGC GCTTCTGTGA TCTGCCGGGT ATTATGCAAC ACTTTACAAT TCCTGCGTCG GCCTTTGATA AATCCGTCTT TGACGACGGC CTTGCATTTG ATGGCAGCTC CATCCGGGGA TTTCAAAGTA TTCATGAATC CGACATGCTG TTACTGCCGG ATCCGGAAAC AGCTCGTATT GATCCCTTTC GTGCGGCAAA AACCCTGAAT ATTAATTTCT TTGTGCATGA TCCTTTCACC CTGGAACCGT ACAGCCGCGA TCCTCGCAAC ATCGCCCGTA AAGCGGAAAA CTATCTGATC TCAACTGGAA TTGCTGATAC CGCGTACTTT GGCGCAGAGG CCGAGTTCTA CATTTTTGAC AGCGTATCTT TCGACTCTCG CGCGAACGGC AGCTTTTACG AAGTGGATGC AATCTCGGGG TGGTGGAACA CCGGGGCCGC TACCGAAGCT GATGGCTCGC CAAATCGCGG CTACAAGGTA CGCCACAAGG GCGGTTACTT TCCTGTCGCT CCAAACGACC AGTACGTGGA TCTGCGTGAC AAGATGCTCA CCAACCTGAT TAATTCCGGC TTTATTCTGG AAAAAGGCCA TCATGAGGTT GGGAGTGGGG GTCAGGCAGA AATTAACTAC CAATTTAACT CCCTGTTACA TGCTGCGGAC GACATGCAAC TGTACAAATA CATCATCAAA AACACGGCTT GGCAAAACGG TAAAACGGTG ACATTTATGC CGAAGCCACT GTTTGGAGAC AATGGCTCTG GCATGCATTG TCACCAATCG CTTTGGAAAG ATGGAGCGCC TCTGATGTAT GATGAAACCG GCTATGCTGG GCTGAGCGAT ACGGCCCGCC ACTATATTGG TGGGTTACTG CACCATGCGC CATCACTGCT GGCTTTTACG AATCCGACCG TTAATAGTTA TAAACGCTTG GTTCCGGGAT ACGAAGCGCC AATTAACCTG GTGTATAGCC AGCGTAACCG CTCCGCTTGC GTTCGTATCC CGATCACCGG CTCTAATCCA AAAGCAAAAC GTTTAGAGTT CCGTTCGCCC GACAGTAGTG GTAACCCTTA TTTGGCGTTT AGTGCGATGC TGATGGCAGG CTTGGACGGC ATTAAAAATA AAATCGAGCC TCAGGCACCG GTCGATAAAG ATTTATATGA ACTTCCGCCC GAAGAGGCGG CATCCATCCC GCAGACTCCG ACGCAACTGT CGGATGTAAT TGATCGCCTG GAGGCCGATC ATGAGTACCT GACGGAGGGG GGTGTCTTCA CGAACGATCT GATTGAAACC TGGATCTCGT TCAAACGTGA AAACGAAATT GAACCTGTTA ATATTCGCCC GCACCCTTAT GAATTTGCCC TGTATTATGA TGTGTAA

*GC% Content for gene (codon optimized): 49.756%

Do Not Need this info for Spring (but still copy these lines to your Target page for now)
Primer design results for pNIC-Bsa4 cloning (list seqeunces of all of your ~40 nt long primers)
(link to DNA Works output text file - that should be saved in your Google Docs folder after you did the primer design protocol)
-- Ask a mentor, Dr. B, or a fellow researcher -how to link a GDocs file if you are not sure how to.

Primer design results for 'tail' primers (this is just 2 sequences):